Mammoth Uncensored Word List:
13 words that are 21 letters long beginning with q in the mammoth uncensored word list.

quadragintacentillion quadringentilliardths quattuordecilliardths quattuortrigintillion quattuorvigintillions quinquagintilliardths quinquanonagintillion quinquaoctogintillion quinquasexagintillion quinquatrigintilliard quinquatrigintillions quinquavigintilliards quinquavigintillionth