Mammoth Uncensored Word List:
10 words that are 19 letters long beginning with q in the mammoth uncensored word list.

quadragintilliardth quadragintillionths quadringentilliards quadringentillionth quattuordecilliards quattuordecillionth quinquadecillionths quinquagintilliards quinquagintillionth quinquavigintillion