This is a list of all 21 letter words that start with the letter z contained in the mammoth uncensored word list. Because this list is uncensored, you may be offended by some words. If so, use instead.

Mammoth Uncensored Word List:
1 word that is 21 letters long beginning with z in the mammoth uncensored word list.

zygomaticoauricularis
 
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allabcdeghilmnopqstuz